Catalytic (3 + 2) umpolung annulations of α-thioacyl carbenes with aryl isothiocyanates-Reference-Cited by-同舟云学术

Catalytic (3 + 2) umpolung annulations of α-thioacyl carbenes with aryl isothiocyanates

Published:2022 Issue:57 Volume:58 Page:7980-7983
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Dong Ziyang¹^ORCID,Ma Meng-Yao¹,Xu Jiaxi¹^ORCID,Yang Zhanhui¹^ORCID

Affiliation:

1. Department of Organic Chemistry, College of Chemistry, Beijing University of Chemical Technology, Beijing, 100029, P. R. China

Abstract

As masked S-electrophilic thia-1,3-dipoles, 1,2,3-thiadiazoles undergo denitrogenative (3 + 2) umpolung transannulations with aryl isothiocyanates, regio- and stereoselectively.

Funder

Central University Basic Research Fund of China

National Natural Science Foundation of China

Natural Science Foundation of Beijing Municipality

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC02882D

Reference44 articles.

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3. Rhodium Thiavinyl Carbenes from 1,2,3-Thiadiazoles Enable Modular Synthesis of Multisubstituted Thiophenes

4. Regioselective Synthesis of Dihydrothiophenes and Thiophenes via the Rhodium-Catalyzed Transannulation of 1,2,3-Thiadiazoles with Alkenes

5. Synthesis of Isothiazole via the Rhodium-Catalyzed Transannulation of 1,2,3-Thiadiazoles with Nitriles

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