A spectroscopic study of the excited state proton transfer processes of (8-bromo-7-hydroxyquinolin-2-yl)methyl-protected phenol in aqueous solutions

Author:

Huang Jinqing123,Muliawan Adna P.456,Ma Jiani789103,Li Ming De123,Chiu Hoi Kei123,Lan Xin123,Deodato Davide456,Phillips David Lee123,Dore Timothy M.456111ORCID

Affiliation:

1. Department of Chemistry

2. The University of Hong Kong

3. People's Republic of China

4. New York University Abu Dhabi

5. Abu Dhabi

6. United Arab Emirates

7. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education

8. College of Chemistry and Materials Science

9. Northwest University

10. Xi'an

11. University of Georgia

Abstract

Spectroscopy and DFT calculations elucidate a mechanism involving early and rapid ESPTs for the photolytic release of phenol from BHQ-OPh.

Funder

Division of Chemistry

Publisher

Springer Science and Business Media LLC

Subject

Physical and Theoretical Chemistry

Reference37 articles.

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2. Biologically Active Molecules with a “Light Switch”

3. Photoremovable Protecting Groups in Chemistry and Biology: Reaction Mechanisms and Efficacy

4. Two-photon uncaging: New prospects in neuroscience and cellular biology

5. T. M. Dore and H. C.Wilson, in Photosensitive Molecules for Controlling Biological Function, ed. J. J. Chambers and R. H. Kramer, Humana Press, New York, 2011, pp. 57–92

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