Electronic structure and rovibrational predissociation of the 21Π state in KLi

Abstract

Adiabatic potential energy curves of the 3¹Σ⁺, 3³Σ⁺, 2¹Π and 2³Π states correlating for large internuclear distance with the K(4s) + Li(2p) atomic asymptote were calculated. Lifetimes of the quasi-bound rovibrational states of the 2¹Π state were determined by explicit time propagation.