Minisci C–H alkylation of N-heteroarenes with aliphatic alcohols via β-scission of alkoxy radical intermediates-Reference-Cited by-同舟云学术

Minisci C–H alkylation of N-heteroarenes with aliphatic alcohols via β-scission of alkoxy radical intermediates

Published:2019 Issue:18 Volume:6 Page:3205-3209
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Hu Xiafei¹²³⁴⁵,Li Guo-Xing¹²³⁴⁵,He Gang¹²³⁴⁵,Chen Gong¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory and Institute of Elemento-Organic Chemistry

2. College of Chemistry

3. Nankai University

4. Tianjin 300071

5. China

Abstract

A generally applicable method for Minisci C–H alkylation of N-heteroarenes with aliphatic alcohols via β-scission of alkoxy radical intermediates under photoredox-catalyzed conditions.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Tianjin City

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00786E

Reference49 articles.

1. Status and prospects in higher alcohols synthesis from syngas

2. If CH Bonds Could Talk: Selective CH Bond Oxidation

3. CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

4. O–H hydrogen bonding promotes H-atom transfer from α C–H bonds for C-alkylation of alcohols

5. Stereoselective Construction of the Tetrahydrofuran Nucleus by Alkoxyl Radical Cyclizations

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