Novel non-spherical deltahedra in tritungstaboranes related to the experimentally known Cp*3W3(H)B8H8-Reference-Cited by-同舟云学术

Novel non-spherical deltahedra in tritungstaboranes related to the experimentally known Cp*3W3(H)B8H8

Published:2017 Issue:19 Volume:41 Page:10640-10651
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Attia Amr A. A.¹²³⁴⁵,Lupan Alexandru¹²³⁴⁵,Bruce King R.⁶⁷⁸⁹^ORCID

Affiliation:

1. Department of Chemistry

2. Faculty of Chemistry and Chemical Engineering

3. Babeş-Bolyai University

4. Cluj-Napoca

5. Romania

6. Department of Chemistry and Center for Computational Quantum Chemistry

7. University of Georgia

8. Athens

9. USA

Abstract

Low-energy Cp₃W₃(H)B_n−3H_n−3 (Cp = η⁵-C₅H₅; n = 5 to 12) structures have central W₃B_n−3 deltahedra with superimposed bonded W₃ triangles. Five lowest-energy Cp₃W₃(H)B₈H₈ structures all have the same central W₃B₈ deltahedron as found in the experimental Cp*₃W₃(H)B₈H₈ (Cp* = η⁵-Me₅C₅) structure.

Funder

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C7NJ01801K

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