Rh-catalyzed aerobic oxidative cyclization of anilines, alkynes, and CO-Reference-Cited by-同舟云学术

Rh-catalyzed aerobic oxidative cyclization of anilines, alkynes, and CO

Published:2017 Issue:9 Volume:8 Page:6266-6273
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Li Xinyao¹²³⁴⁵,Pan Jun¹²³⁴⁵,Wu Hao¹²³⁴⁵,Jiao Ning¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Natural and Biomimetic Drugs

2. Peking University

3. School of Pharmaceutical Sciences

4. Beijing 100191

5. China

Abstract

We describe a novel Rh-catalyzed C–H cyclization of a wide range of anilines with alkynes and CO. Particularly, simple primary anilines and readily prepared tertiary anilines can be easily converted to quinolin-2(1H)-ones via C–N bond cleavage.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC02181J

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