Identification of structural changes in CaCu3Ti4O12 on high energy ball milling and their effect on photocatalytic performance

Author:

Bartoletti Andrea12,Gondolini Angela1,Sangiorgi Nicola1ORCID,Aramini Matteo3,Ardit Matteo4,Rancan Marzio5,Armelao Lidia26,Kondrat Simon A.7ORCID,Sanson Alessandra1

Affiliation:

1. Institute of Science and Technology for Ceramics (ISTEC) of the National Research Council (CNR), Via Granarolo 64, I-48018 Faenza (RA), Italy

2. Department of Chemical Sciences, Università degli Studi di Padova, Via Marzolo 1, 35131, Padova, Italy

3. Diamond Light Source, Harwell Science and Innovation Campus, Chilton, Didcot, OX11 0DE, UK

4. Department of Physics and Earth Sciences, University of Ferrara, Via Saragat 1, Ferrara 44122, Italy

5. Institute of Condensed Matter Chemistry and Technologies for Energy (ICMATE), National Research Council (CNR), c/o Department of Chemistry, University of Padova, Via F. Marzolo 1, 35131 Padova, Italy

6. Department of Chemical Sciences and Materials Technologies (DSCTM), National Research Council (CNR), Italy

7. Department of Chemistry, Loughborough University, Loughborough, Leicestershire, LE113TU, UK

Abstract

Milling increased the surface-area normalised photocatalytic performance of a perovskite, through inclusion of defects as determined by X-ray absorption spectroscopy.

Funder

Royal Society

Engineering and Physical Sciences Research Council

European Regional Development Fund

Wolfson Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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