syn-Selective crotylation of aldehydes using bismuth-crotyl bromide-(1-butyl-3-methylimidazolium bromide) combination: some synthetic applications

Author:

Goswami Dibakar1234,Koli Mrunesh R.1234,Chatterjee Sucheta1234,Chattopadhyay Subrata1234,Sharma Anubha1234ORCID

Affiliation:

1. Bio-Organic Division

2. Bhabha Atomic Research Centre

3. Mumbai 400085

4. India

Abstract

Highly syn-selective crotylation of aldehydes was achieved using Bi-[bmim][Br]-crotyl bromide combination, leading to an easy, stereodivergent method to synthesise important targets.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference184 articles.

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3. Recent Progress in the Chemical Synthesis of Antibiotics, ed. G. Lukacs and M. Ohno, Springer, Berlin, 1990, vol. 1

4. Octalactins A and B: cytotoxic eight-membered-ring lactones from a marine bacterium, Streptomyces sp

5. Diastereoselective Allylation and Crotylation Reactions of Aldehydes with Potassium Allyl- and Crotyltrifluoroborates under Lewis Acid Catalysis

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