Insight into the acidic group-induced nitration mechanism of 2-methyl-4,6-dihydroxypyrimidine (MDP) with nitronium-Reference-Cited by-同舟云学术

Insight into the acidic group-induced nitration mechanism of 2-methyl-4,6-dihydroxypyrimidine (MDP) with nitronium

Published:2016 Issue:83 Volume:6 Page:80145-80157
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Wang Kuan¹²³⁴,Chen Jian-Gang¹²³⁴,Wang Bozhou⁵⁶³⁴,Ji Yueping⁵⁶³⁴,Liu Fengyi¹²³⁴,Liu Zhao-Tie¹²³⁴,Wang Wenliang¹²³⁴,Liu Zhong-Wen¹²³⁴,Hao Zhengping¹²³⁴⁷,Lu Jian⁵⁶³⁴

Affiliation:

1. Key Laboratory of Applied Surface and Colloid Chemistry (MOE) and School of Chemistry & Chemical Engineering

2. Shaanxi Normal University

3. Xi'an

4. China

5. Department of Catalytic Technology

6. Institute of Xi'an Modern Chemistry

7. Research Centre for Eco-Environmental Science

Abstract

An incredible HSO₄⁻-induction to the title nitration is proposed. The charge distribution/fluctuation provides a favorable nitration path.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA18842G

Reference57 articles.

1. Synthesis and reactions of 1,1-diamino-2,2-dinitroethylene

2. Study on Reactions of 2-(Dinitromethylene)-4,5-imidazolidinedione

3. Preparation of Spherical Particles of 1,1-Diamino-2,2-dinitroethene (FOX-7) Using a Micellar Nanoreactor

4. On the Synthesis of 1,1-Diamino-2,2-dinitroethene (FOX-7) by Nitration of 4,6-Dihydroxy-2-methylpyrimidine

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