Mapping the influence of ligand electronics on the spectroscopic and <sup>1</sup>O<sub>2</sub> sensitization characteristics of Pd(<scp>ii</scp>) biladiene complexes bearing phenyl–alkynyl groups at the 2- and 18-positions-Reference-Cited by-同舟云学术

Mapping the influence of ligand electronics on the spectroscopic and ¹O₂ sensitization characteristics of Pd(ii) biladiene complexes bearing phenyl–alkynyl groups at the 2- and 18-positions

Published:2023 Issue:22 Volume:52 Page:7512-7523
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Martin Maxwell I.¹,Pham Trong-Nhan¹^ORCID,Ward Kaytlin N.¹,Rice Anthony T.¹,Hertler Phoebe R.¹,Yap Glenn P. A.¹^ORCID,Gilmartin Philip H.¹,Rosenthal Joel¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of Delaware, Newark, DE, 19716, USA

Abstract

Extension of biladiene complexes via introduction of phenyl-alkynyl groups at the 2- and 18-positions generates new platforms that efficiently sensitize formation of 1O2 using long-visible light.

Funder

U.S. Department of Energy

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00691C

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