Mapping the influence of ligand electronics on the spectroscopic and 1O2 sensitization characteristics of Pd(ii) biladiene complexes bearing phenyl–alkynyl groups at the 2- and 18-positions

Author:

Martin Maxwell I.1,Pham Trong-Nhan1ORCID,Ward Kaytlin N.1,Rice Anthony T.1,Hertler Phoebe R.1,Yap Glenn P. A.1ORCID,Gilmartin Philip H.1,Rosenthal Joel1ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of Delaware, Newark, DE, 19716, USA

Abstract

Extension of biladiene complexes via introduction of phenyl-alkynyl groups at the 2- and 18-positions generates new platforms that efficiently sensitize formation of 1O2 using long-visible light.

Funder

U.S. Department of Energy

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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