“Converting” an hexametallic MnIII wheel to a dodecametallic MnIII wheel via ligand oximation

Author:

Sanz Sergio123,Frost Jamie M.123,Pitak Mateusz B.45678,Coles Simon J.45678,Piligkos Stergios91011,Lusby Paul J.123,Brechin Euan K.123

Affiliation:

1. EaStCHEM School of Chemistry

2. The University of Edinburgh

3. Edinburgh, UK

4. UK National Crystallography Service

5. Chemistry

6. Faculty of Natural and Environmental Sciences

7. University of Southampton

8. Southampton, UK

9. Department of Chemistry

10. University of Copenhagen

11. , Denmark

Abstract

Ligand oximation “converts” an hexametallic MnIII wheel into a dodecametallic MnIII wheel, while the magnetic exchange switches from ferro- to antiferromagnetic.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference14 articles.

1. Magneto-Structural Correlations in Exchange-Coupled Systems , ed. D. Gatteschi , O. Kahn and R. D. Willet , Reidel Press , Dordrecht , 1985

2. Synthesis of 3d Metallic Single-Molecule Magnets

3. Strategies towards single molecule magnets based on lanthanide ions

4. A. K. Boudalis , Y.Sanakis , C. P.Raptopoulou and V.Psycharis , in Magnetism and Superconductivity in Low-Dimensional Systems: Utilization in Future Applications , ed. D. Stamopoulos , Nova Science Publishers Inc. , New York , 2008 , pp. 1–77

5. Molecular Cluster Magnets , ed. R. E. P. Winpenny , World Scientific Books , Singapore , 2011

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