Palladium catalyzed divergent cycloadditions of vinylidenecyclopropane-diesters with methyleneindolinones enabled by zwitterionic π-propargyl palladium species-Reference-Cited by-同舟云学术

Palladium catalyzed divergent cycloadditions of vinylidenecyclopropane-diesters with methyleneindolinones enabled by zwitterionic π-propargyl palladium species

Published:2021 Issue:39 Volume:57 Page:4783-4786
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Niu Ben¹²³⁴⁵,Wei Yin⁶⁷⁸⁹¹⁰,Shi Min¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory for Advanced Materials and Institute of Fine Chemicals

2. School of Chemistry & Molecular Engineering

3. East China University of Science and Technology

4. Shanghai 200237

5. People's Republic of China

6. State Key Laboratory of Organometallic Chemistry

7. Center for Excellence in Molecular Synthesis

8. University of Chinese Academy of Sciences

9. Shanghai Institute of Organic Chemistry

10. Chinese Academy of Sciences

Abstract

An in situ generated unprecedented zwitterionic π-propargyl palladium species in a switchable process between (3+2) and (4+2) cycloadditions can be achieved by changing the phosphine ligand.

Funder

Chinese Academy of Sciences

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC01453F

Reference36 articles.

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3. New synthetic reactions of allyl alkyl carbonates, allyl .beta.-keto carboxylates, and allyl vinylic carbonates catalyzed by palladium complexes

4. Synthesis of Functionalized Cyclic Molecules by Palladium-Catalyzed Cyclization of Propargylic Esters with Bis-nucleophiles

5. Synthesis, Structure, and Reactivity of Neutral η3-Propargylpalladium Complexes

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