Synthesis and catalytic performance of nickel phosphinite pincer complexes in deoxygenative hydroboration of amides-Reference-Cited by-同舟云学术

Synthesis and catalytic performance of nickel phosphinite pincer complexes in deoxygenative hydroboration of amides

Published:2023 Issue:9 Volume:52 Page:2872-2886
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Adilkhanova Aziza¹²,Frolova Valeriya F.¹^ORCID,Yessengazin Azamat¹^ORCID,Öztopçu Özgür¹,Gudun Kristina A.¹^ORCID,Segizbayev Medet³,Matsokin Nikita A.⁴^ORCID,Dmitrienko Anton³⁵,Pilkington Melanie³^ORCID,Khalimon Andrey Y.¹^ORCID

Affiliation:

1. Department of Chemistry, School of Sciences and Humanities, Nazarbayev University, 53 Kabanbay Batyr Avenue, Astana 010000, Kazakhstan

2. School of Mining and Geosciences, Nazarbayev University, 53 Kabanbay Batyr Avenue, Astana 010000, Kazakhstan

3. Department of Chemistry, Brock University, 1812 Sir Isaac Brock Way, St Catharines, Ontario L2S 3A1, Canada

4. Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow 119991, Russia

5. Department of Chemistry and Biochemistry, University of Windsor, 401 Sunset Avenue, Windsor, Ontario N9B 3P4, Canada

Abstract

A series of POCNR POCNR2 and POCOP pincer complexes of Ni(ii) were prepared and their catalytic activities in deoxygenative hydroboration of amides were investigated, resulting in efficient and selective deoxygenation of secondary amides to amines.

Funder

Ministry of Education and Science of the Republic of Kazakhstan

Nazarbayev University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03801C

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