Metal ion influences distortion of the ligand in the structure of [M{2-MeO(O)CC6H4NHC(S)NP(S)(OiPr)2}2] (M = ZnII, CdII) complexes: a driving force for intermolecular aggregation-Reference-Cited by-同舟云学术

Metal ion influences distortion of the ligand in the structure of [M{2-MeO(O)CC6H4NHC(S)NP(S)(OiPr)2}2] (M = ZnII, CdII) complexes: a driving force for intermolecular aggregation

Published:2015 Issue:31 Volume:44 Page:14101-14109
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Safin Damir A.¹²³⁴,Babashkina Maria G.¹²³⁴,Bolte Michael⁵⁶⁴,Mitoraj Mariusz P.⁷⁸⁹¹⁰¹¹,Klein Axel¹²³⁴

Affiliation:

1. Institut für Anorganische Chemie

2. Universität zu Köln

3. D-50939 Köln

4. Germany

5. Institut für Anorganische Chemie J.-W.-Goethe-Universität

6. Frankfurt/Main

7. Department of Theoretical Chemistry

8. Faculty of Chemistry

9. Jagiellonian University

10. 30-060 Cracow

11. Poland

Abstract

Reaction of the deprotonated 2-MeO(O)CC₆H₄NHC(S)NHP(S)(OiPr)₂ (HL) with Zn^II or Cd^II leads to [ZnL2] and [CdL2]. The nature of the metal cation (Zn^IIvs. Cd^II) drives the supramolecular aggregation of molecules in the crystal structure.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02189H

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