Nitroaldol (Henry) reaction of 2-oxoaldehydes with nitroalkanes as a strategic step for a useful, one-pot synthesis of 1,2-diketones-Reference-Cited by-同舟云学术

Nitroaldol (Henry) reaction of 2-oxoaldehydes with nitroalkanes as a strategic step for a useful, one-pot synthesis of 1,2-diketones

Published:2015 Issue:46 Volume:5 Page:36652-36655
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Palmieri Alessandro¹²³⁴⁵,Gabrielli Serena¹²³⁴⁵,Sampaolesi Susanna¹²³⁴⁵,Ballini Roberto¹²³⁴⁵

Affiliation:

1. “Green Chemistry Group”

2. School of Science and Technology

3. Chemistry Division

4. University of Camerino

5. 62032 Camerino

Abstract

The nitroaldol (Henry) reaction of 2-oxoaldehydes with a variety of nitroalkanes, under basic heterogeneous conditions and microwave irradiation, affords 1,2-diketones in a one-pot way.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA03772G

Reference54 articles.

1. Cyclic 1,2-Diketones as Building Blocks for Asymmetric Synthesis of Cycloalkenones

2. Stereocontrolled Photocyclization of 1,2-Diketones: Application of a 1,3-Acetyl Group Transfer Methodology to Carbohydrates

3. Photoaddition Reactions of 1,2-Diketones with Silyl Ketene Acetals. Formation of β-Hydroxy-γ-ketoesters

4. Indium-Mediated Regio- and Diastereoselective Reduction of Norbornylα-Diketones

5. Allosteric Akt (PKB) inhibitors: discovery and SAR of isozyme selective inhibitors

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