Titanium-based phenoxy-imine catalyst for selective ethylene trimerization: effect of temperature on the activity, selectivity and properties of polymeric side products
Author:
Affiliation:
1. UMR 5265
2. Laboratoire de Chimie Catalyse Polymères et Procédés (C2P2)
3. Univ. Lyon
4. Université Claude Bernard Lyon 1
5. 69616 Villeurbanne
6. IFP Energies nouvelles
7. 69360 Solaize
8. France
Abstract
A thermal switch of selectivity for a phenoxy-imine titanium catalyst was studied by combining kinetic studies and a “polymer-to-catalyst” approach.
Funder
IFP Energies Nouvelles
Région Auvergne-Rhône-Alpes
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CY/C9CY02056J
Reference32 articles.
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2. Oligomerization of Monoolefins by Homogeneous Catalysts
3. Selective ethylene oligomerization: Recent advances in chromium catalysis and mechanistic investigations
4. Role of Homogeneous Catalysis in Oligomerization of Olefins : Focus on Selected Examples Based on Group 4 to Group 10 Transition Metal Complexes
5. Olefin Oligomerization via Metallacycles: Dimerization, Trimerization, Tetramerization, and Beyond
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