Two- and three-dimensional β,β′-N-heterocycle fused porphyrins: concise construction, singlet oxygen production and electro-catalytic hydrogen evolution reaction

Author:

Fan Yan1ORCID,Zeng Zhiming1,Shu Hui1,Zhou Mingbo1,Xu Ling1,Rao Yutao1,Gu Tingting2,Liang Xu2ORCID,Zhu Weihua2ORCID,Song Jianxin1ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering, Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education of China), Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha 410081, P. R. China

2. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, P. R. China

Abstract

A series of 2D and 3D porphyrins fused with N-heterocycles were prepared by palladium-catalyzed. Photophysical and electrochemical properties, 1O2 production and electrocatalytic HER behaviours of the representative porphyrins were investigated.

Funder

Hunan Provincial Science and Technology Department

Scientific Research Foundation of Hunan Provincial Education Department

Science and Technology Program of Hunan Province

Hunan Normal University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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