ROESY and 13C NMR to distinguish between <scp>d</scp>- and <scp>l</scp>-rhamnose in the α-<scp>d</scp>-Manp-(1 → 4)-β-Rhap-(1 → 3) repeating motif-Reference-Cited by-同舟云学术

ROESY and ¹³C NMR to distinguish between d- and l-rhamnose in the α-d-Manp-(1 → 4)-β-Rhap-(1 → 3) repeating motif

Published:2022 Issue:14 Volume:20 Page:2964-2980
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Davidson Jeffrey¹,Gauthier-Signore Charles¹,Bishop Kevin P.²^ORCID,Wicks Christopher¹,Monteiro Mario A.¹,Roy Pierre-Nicholas²^ORCID,Auzanneau France-Isabelle¹^ORCID

Affiliation:

1. Department of Chemistry, University of Guelph, Guelph, Ontario N1G 2W1, Canada

2. Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada

Abstract

CH3-6 of l-Rha and H-2 of d-Man give ROE correlation in the α-d-Manp-(1 → 4)-l-Rhap motif. C-2 in d-Man is shifted upfield in the 13C NMR spectrum of the β-d-Rhap-(1 → 3)-d-Manp motif.

Funder

Natural Sciences and Engineering Research Council of Canada

Ontario Ministry of Research and Innovation

Canada Research Chairs

Canada Foundation for Innovation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB00131D

Reference48 articles.