Discovery of a ternary pseudobrookite phase in the earth-abundant Ti–Zn

Discovery of a ternary pseudobrookite phase in the earth-abundant Ti–Zn–O system

Published:2016 Issue:4 Volume:45 Page:1572-1581
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Perry Nicola H.¹²³⁴⁵,Stevanovic Vladan⁶⁷⁸⁹⁷,Lim Linda Y.¹⁰¹¹¹²⁸,Mason Thomas O.⁵¹³¹⁴⁸

Affiliation:

1. International Institute for Carbon-Neutral Energy Research (WPI-I2CNER)

2. Kyushu University

3. Nishi-ku Fukuoka

4. Japan

5. Department of Materials Science and Engineering

6. Colorado School of Mines

7. Golden

8. USA

9. National Renewable Energy Laboratory

10. Materials Science and Engineering Department

11. Stanford University

12. Stanford

13. Northwestern University

14. Evanston

Abstract

We apply a combined theoretical and experimental approach to the search for “missing”, stable materials within the ternary Zn–Ti–O chemical system, leading to the discovery of a new pseudobrookite phase, Zn_xTi_3−xo_5−δ.

Funder

Ministry of Education, Culture, Sports, Science, and Technology

Division of Materials Research

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04145G

Reference49 articles.

1. G. Bergerhoff and I. D.Brown, in Crystallographic Databases, ed. F. H. Allenet al. (Hrsg.), International Union of Crystallography, Chester, 1987

2. Theoretical Prediction and Experimental Realization of New Stable Inorganic Materials Using the Inverse Design Approach

3. Prediction and accelerated laboratory discovery of previously unknown 18-electron ABX compounds

4. Synthesis, Computed Stability, and Crystal Structure of a New Family of Inorganic Compounds: Carbonophosphates

5. Novel mixed polyanions lithium-ion battery cathode materials predicted by high-throughput ab initio computations

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