Room temperature carbon(CO)–carbon(α) bond activation of ketones by rhodium(ii) porphyrins with water

Author:

Lee Siu Yin1234,Feng Shiyu1234,Chan Kin Shing1234

Affiliation:

1. Department of Chemistry

2. The Chinese University of Hong Kong

3. Shatin, New Territories

4. People's Republic of China

Abstract

The mild and selective aliphatic C(CO)–C(α) bond activation (CCA) of ketones was successfully achieved at room temperature using rhodium(ii) porphyrins in the presence of H2O.

Funder

Research Grants Council, University Grants Committee, Hong Kong

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference31 articles.

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2. M. Murakam and Y.Ito, in Topics in Organometallic Chemistry, Vol. 3, Cleavage of Carbon–Carbon Single Bonds by Transition Metals, ed. S. Murai, Springer-Verlag, Berlin Heidelberg, 1999, pp. 97–129

3. Activation of a carbon–carbon bond in solution by transition-metal insertion

4. Metal Insertion into C−C Bonds in Solution

5. L. E. J. Brouwer , The Petroleum Handbook, Shell Co. of Hong Kong, London, 5th edn, 1966

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