Synthesis of [60]fullerene-fused dihydrobenzooxazepinesviathe palladium-catalyzed oxime-directed C–H bond activation and subsequent electrochemical functionalization
Author:
Affiliation:
1. CAS Key Laboratory of Soft Matter Chemistry
2. Hefei National Laboratory for Physical Sciences at Microscale
3. and Department of Chemistry
4. University of Science and Technology of China
5. Hefei
Abstract
The palladium-catalyzed heteroannulation of [60]fullerene with oximes affords the unprecedented seven-membered [60]fullerene-fused dihydrobenzooxazepines, which can be further derivatized electrochemically.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/QO/D0QO00710B
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