Detection of σ-alkane complexes of manganese by NMR and IR spectroscopy in solution: (η5-C5H5)Mn(CO)2(ethane) and (η5-C5H5)Mn(CO)2(isopentane)-Reference-Cited by-同舟云学术

Detection of σ-alkane complexes of manganese by NMR and IR spectroscopy in solution: (η5-C5H5)Mn(CO)2(ethane) and (η5-C5H5)Mn(CO)2(isopentane)

Published:2015 Issue:1 Volume:6 Page:418-424
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Torres Olga¹²³⁴,Calladine James A.⁵⁶⁷⁴,Duckett Simon B.¹²³⁴,George Michael W.⁵⁶⁷⁴,Perutz Robin N.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of York

3. York YO10 5DD

4. UK

5. School of Chemistry

6. University of Nottingham

7. Nottingham NG7 2RD

Abstract

Irradiation (355 nm) of CpMn(CO)₃in liquid ethane at 133 K yields CpMn(CO)₂(η²-C–H-ethane) characterised by IR and¹H NMR spectroscopy with a lifetime ofca. 360 s; the corresponding isopentane complex is formed in propane/isopentane mixtures and exists in three isomeric forms.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC02869D

Reference66 articles.

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