Barrierless methane-to-methanol conversion: the unique mechanism of AlO+-Reference-Cited by-同舟云学术

Barrierless methane-to-methanol conversion: the unique mechanism of AlO+

Published:2020 Issue:26 Volume:22 Page:14544-14550
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Sweeny Brendan C.¹²³⁴,McDonald David C.¹²³⁴,Ard Shaun G.⁵²³⁴,Viggiano Albert A.⁵²³⁴,Shuman Nicholas S.⁵²³⁴^ORCID

Affiliation:

1. NRC Postdoc at Air Force Research Laboratory

2. Space Vehicles Directorate

3. Kirtland Air Force Base

4. USA

5. Air Force Research Laboratory

Abstract

Alcohol for free? Aluminum can: aluminum enables oxygen transfer to methane via a unique, barrierless formation of R-Al–MeOH. The key Al–MeOH bond strength is tunable by controlling the acidity of the Al via electron-donating or withdrawing R groups.

Funder

Air Force Office of Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP02316G

Reference37 articles.

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