Understanding the domino reaction between 1-diazopropan-2-one and 1,1-dinitroethylene. A molecular electron density theory study of the [3 + 2] cycloaddition reactions of diazoalkanes with electron-deficient ethylenes

Author:

Domingo Luis R.1234ORCID,Ríos-Gutiérrez Mar1234ORCID,Emamian Saeedreza56789

Affiliation:

1. Department of Organic Chemistry

2. University of Valencia

3. E-46100 Burjassot

4. Spain

5. Chemistry Department

6. Shahrood Branch

7. Islamic Azad University

8. Shahrood

9. Iran

Abstract

The domino reaction between 1-diazopropan-2-one and 1,1-dinitroethylene yielding a pyrazole and a gem-dinitrocyclopropane has been studied using molecular electron density theory.

Funder

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference52 articles.

1. W. Carruthers , Some Modern Methods of Organic Synthesis, Cambridge University Press, Cambridge, 2nd edn, 1978

2. W. Carruthers , Cycloaddition Reactions in Organic Synthesis, ed. J. E. Baldwin and P. D. Magnus, Pergamon, Oxford, 1990

3. Synthetic Applications of 1,3-Dipolar Cycloaddition Chemistry Toward Heterocycles and Natural Products, ed. A. Padwa and W. H. Pearson, John Wiley & Sons, Inc, 2002, vol. 59

4. Asymmetric 1,3-Dipolar Cycloaddition Reactions

5. Einwirkung von Diazoessigäther auf die Aether ungesättigter Säuren

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