Transition metal- and organophotocatalyst-free perfluoroalkylation reaction of amino(hetero)aromatics initiated by the complex [(TMEDA)I·I3] and visible light-Reference-Cited by-同舟云学术

Transition metal- and organophotocatalyst-free perfluoroalkylation reaction of amino(hetero)aromatics initiated by the complex [(TMEDA)I·I3] and visible light

Published:2017 Issue:1 Volume:7 Page:266-274
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Yerien Damian E.¹²³⁴⁵,Conde Romina¹²³⁴⁵,Barata-Vallejo Sebastian¹²³⁴⁵,Camps Bruno¹²³⁴⁵,Lantaño Beatriz¹²³⁴⁵,Postigo Al¹²³⁴⁵^ORCID

Affiliation:

1. Universidad de Buenos Aires

2. Facultad de Farmacia y Bioquímica

3. Departamento de Química Orgánica

4. CP 1113-Buenos Aires

5. Argentina

Abstract

Radical initiation for the perfluoroalkylation reaction of amino(hetero)aromatics has been accomplished employing the complex [(TMEDA)I·I₃] and visible light.

Funder

Secretaria de Ciencia y Tecnica, Universidad de Buenos Aires

Consejo Nacional de Investigaciones Científicas y Técnicas

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C6RA24786E

Reference24 articles.

1. Reactions of trifluoromethyl bromide and related halides: part 10. Perfluoroalkylation of aromatic compounds induced by sulphur dioxide radical anion precursors

2. Copper(I) Oxide Mediated Perfluoroalkylation of Anilines