Utilization of a Pt(ii) di-yne chromophore incorporating a 2,2′-bipyridine-5,5′-diyl spacer as a chelate to synthesize a green and red emitting d–f–d heterotrinuclear complex

Author:

Al-Busaidi Idris Juma1234ORCID,Ilmi Rashid1234ORCID,Dutra José D. L.51678ORCID,Oliveira Willyan F.51678,Haque Ashanul12341ORCID,Al Rasbi Nawal K.1234,Marken Frank191011ORCID,Raithby Paul R.191011ORCID,Khan Muhammad S.1234

Affiliation:

1. Department of Chemistry

2. Sultan Qaboos University

3. Al Khoud 123

4. Oman

5. Pople Computational Chemistry Laboratory

6. UFS

7. 49100-000 São Cristóvão

8. Brazil

9. University of Bath

10. Bath BA2 7AY

11. UK

Abstract

The heteronuclear trimetallic d–f–d complex [Eu(btfa)3{(Ph)(Et3P)2Pt–CC–R–CC–Pt(Et3P)2(Ph)}] has been synthesized and characterized spectroscopically. The complex displays both red and green emissions in solution.

Funder

The Research Council

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Engineering and Physical Sciences Research Council

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Ministério da Ciência, Tecnologia e Inovação

Fundação de Amparo à Ciência e Tecnologia do Estado de Pernambuco

Fundação de Apoio à Pesquisa e à Inovação Tecnológica do Estado de Sergipe

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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