Excited-state structure of copper phenanthroline-based photosensitizers-Reference-Cited by-同舟云学术

Excited-state structure of copper phenanthroline-based photosensitizers

Published:2021 Issue:47 Volume:23 Page:26729-26736
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Guda Alexander¹,Windisch Johannes²,Probst Benjamin²^ORCID,van Bokhoven Jeroen A.³⁴^ORCID,Alberto Roger²^ORCID,Nachtegaal Maarten³,Chen Lin X.⁵⁶^ORCID,Smolentsev Grigory³^ORCID

Affiliation:

1. The Smart Materials Research Institute, Southern Federal University Rostov-on-Don, 344090, Russia

2. Department of Chemistry, University of Zurich, Zurich, 8057, Switzerland

3. Paul Scherrer Institute, Villigen, 5232, Switzerland

4. Department of Chemistry, ETH Zurich, Zurich 8093, Switzerland

5. Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne 60439, IL, USA

6. Department of Chemistry, Northwestern University, Evanston 60208, IL, USA

Abstract

Pump–probe XAS is used to catch the excited-state of two Cu photosensitizers and 4-coordinated excited states are observed. The exciplex can be involved in the deactivation of [Cu(dmp)2]+ as a non-observable state that forms slower than it decays.

Funder

U.S. Department of Energy

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Russian Foundation for Basic Research

Universität Zürich

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP02823E

Reference44 articles.