Benzoate dioxygenase fromRalstonia eutrophaB9 – unusual regiochemistry of dihydroxylation permits rapid access to novel chirons
Author:
Affiliation:
1. Centre for Sustainable Chemical Technologies
2. University of Bath
3. Claverton Down, UK
4. Department of Biocatalysis and Isotope Chemistry
5. Almac Group Ltd
6. Craigavon, UK
Abstract
Oxidation of benzoic acid by a microorganism expressing benzoate dioxygenase leads to the formation of an unusualipso,orthoarenecis-diol in sufficient quantities to be useful for synthesis.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/QO/C3QO00057E
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