Development of efficient palladium catalysts for alkoxycarbonylation of alkenes

Author:

Liu Jiawang123,Dong Kaiwu123,Franke Robert45367,Neumann Helfried123,Jackstell Ralf123,Beller Matthias123ORCID

Affiliation:

1. Leibniz-Institut für Katalyse an der Universität Rostock

2. 18059 Rostock

3. Germany

4. Evonik Industries AG

5. 45772 Marl

6. Lehrstuhl für Theoretische Chemie

7. 44780 Bochum

Abstract

Palladium catalysts based on 1,3-bis(tert-butyl(pyridin-2-yl)phosphanyl)propane L3 and 1,4-bis(tert-butyl(pyridin-2-yl)phosphanyl)butane L4 allow for the alkoxycarbonylation of sterically hindered olefins including a variety of tetra-, tri- and di-substituted terminal alkenes to afford the desired esters in good to high yields.

Funder

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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