Formation of monomeric Sn(ii) and Sn(iv) perfluoropinacolate complexes and their characterization by 119Sn Mössbauer and 119Sn NMR spectroscopies

Author:

Elinburg Jessica K.1234,Hyre Ariel S.1234,McNeely James1234,Alam Todd M.5674,Klenner Steffen891011,Pöttgen Rainer891011,Rheingold Arnold L.121314154,Doerrer Linda H.1234ORCID

Affiliation:

1. Department of Chemistry

2. Boston University

3. Boston

4. USA

5. Department of Organic Material Science

6. Sandia National Laboratories

7. Albuquerque

8. Institut für Anorganische und Analytische Chemie

9. Universität Münster

10. D-48149 Münster

11. Germany

12. Department of Chemistry and Biochemistry

13. University of California

14. San Diego

15. La Jolla

Abstract

Sn(ii) and Sn(iv) perfluoropinacolate complexes were prepared and characterized with 119Sn NMR,119Sn Mössbauer spectroscopy, and DFT calculations.

Funder

National Science Foundation

National Nuclear Security Administration

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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