Active Ga-catalysts for the ring opening homo- and copolymerization of cyclic esters, and copolymerization of epoxide and anhydrides

Author:

Ghosh Swarup1234,Glöckler Eduard1234,Wölper Christoph1234,Tjaberings Alexander12564,Gröschel André H.12564ORCID,Schulz Stephan1234ORCID

Affiliation:

1. Faculty of Chemistry

2. University of Duisburg-Essen and Center for Nanointegration Duisburg-Essen (CENIDE)

3. D-45141 Essen

4. Germany

5. NanoEnergieTechnikZentrum

6. 47057 Duisburg

Abstract

Ring opening homo- and copolymerization of lactide (LA) and ε-caprolactone (ε-CL) in solution with several Ga catalysts yielded isotactic-enriched PLAs and well defined diblock copolymers by coordination insertion mechanism (CIM).

Funder

Universität Duisburg-Essen

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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