Self-assembly of secondary aryl amides in cocrystals with perfluoroaryl coformers: structural analysis and synthon preferences

Author:

Alfuth Jan1ORCID,Kazimierczuk Katarzyna2ORCID,Połoński Tadeusz1,Olszewska Teresa1ORCID

Affiliation:

1. Department of Organic Chemistry, Faculty of Chemistry, Gdańsk University of Technology, 80-233 Gdańsk, Poland

2. Department of Inorganic Chemistry, Faculty of Chemistry, Gdańsk University of Technology, 80-233 Gdańsk, Poland

Abstract

Lactams 1–3 readily form cocrystals with pentafluorophenol (pfp) or pentafluorobenzoic acid (pfba) and the observed crystal packings result from concerted aryl⋯perfluoroaryl stacking interactions combined with hydrogen bonding.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Reference36 articles.

1. G. R.Desiraju , The Crystal as a Supramolecular Entity , Wiley , Chichester , 1995

2. W.Jones , Organic Molecular Solids: Properties and Applications , CRC Press , Boca Raton , 1997

3. J. K.Whitesell , Organised Molecular Assemblies in the Solid State , Wiley , Chichester , 1999

4. J.-M.Lehn , Supramolecular Chemistry: Concepts and perspectives , Wiley-VCH , Weinheim , 1995

5. Supramolecular Synthons in Crystal Engineering—A New Organic Synthesis

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