Halogen bond and polymorphism in <i>trans</i>-bis(2-iodo-5-halopyridine)dihalocopper(<scp>ii</scp>) complexes: crystallographic, theoretical and magnetic studies-Reference-Cited by-同舟云学术

Halogen bond and polymorphism in trans-bis(2-iodo-5-halopyridine)dihalocopper(ii) complexes: crystallographic, theoretical and magnetic studies

Published:2023 Issue:16 Volume:25 Page:2390-2403
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Awwadi Firas F.¹^ORCID,Alwahsh Manal I.¹^ORCID,Turnbull Mark M.²^ORCID,Landee Christopher P.³^ORCID

Affiliation:

1. Department of Chemistry, The University of Jordan, Amman 11942, Jordan

2. Carlson School of Chemistry and Biochemistry, Clark University, 950 Main St., Worcester, MA 01610, USA

3. Dept. of Physics, Clark University, 950 Main St., Worcester, MA 01610, USA

Abstract

As the halogen atom on position 5 of the 2I5YP ligand gets heavier the probability of crystallizing the syn-conformer increases; 2I5Cl-Cl crystallizes as the anti-conformer whereas 2I5Br-Cl crystallizes as syn- and anti-conformers.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CE/D2CE01711C

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