Facile hydrogen atom abstraction and sulfide formation in a methyl-thiolate capped iron–sulfur–carbonyl cluster
Author:
Affiliation:
1. The University of Texas at Austin
2. Austin
3. USA
Abstract
SAM mediated methyl transfer and subsequent hydrogen atom abstraction are key steps in the biogenesis of nitrogenase. A model system was utilized to demonstrate facile C–H abstraction from a methyl-thiolate containing iron–sulfur cluster with TEMPO.
Funder
Division of Chemistry
Welch Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04098F
Reference22 articles.
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