EPR-derived structures of flavin radical and iron-sulfur clusters from Methylosinus sporium 5 reductase-Reference-Cited by-同舟云学术

EPR-derived structures of flavin radical and iron-sulfur clusters from Methylosinus sporium 5 reductase

Published:2021 Issue:5 Volume:8 Page:1279-1289
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Jeong Han Sol¹²³⁴⁵,Hong Sugyeong¹²³⁴⁵^ORCID,Yoo Hee Seon⁶⁷⁸⁴^ORCID,Kim Jin⁹¹⁰¹¹⁴^ORCID,Kim Yujeong¹²³⁴⁵^ORCID,Yoon Chungwoon⁶⁷⁸⁴^ORCID,Lee Seung Jae⁶⁷⁸⁴^ORCID,Kim Sun Hee¹²³⁴⁵^ORCID

Affiliation:

1. Western Seoul Center

2. Korea Basic Science Institute (KBSI)

3. Seoul 03759

4. Rep. of Korea

5. Department of Chemistry and Nano Science

6. Department of Chemistry and Institute of Molecular Biology and Genetics

7. Jeonbuk National University

8. Jeonju 54896

9. Department of Chemistry

10. Sunchon National University

11. Suncheon 57922

Abstract

The electronic structures of two cofactors, the FAD radical and [2Fe–2S]⁺ of reduced MMOR from Methylosinus sporium strain 5 were investigated by advanced EPR spectroscopy. The findings provide long overdue detailed structural information of MMOR.

Funder

National Research Foundation of Korea

Ministry of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QI/D0QI01334J

Reference60 articles.

1. Alkane Oxidation: Methane Monooxygenases, Related Enzymes, and Their Biomimetics

2. Enzymatic Oxidation of Methane