EPR-derived structures of flavin radical and iron-sulfur clusters from Methylosinus sporium 5 reductase

Author:

Jeong Han Sol12345,Hong Sugyeong12345ORCID,Yoo Hee Seon6784ORCID,Kim Jin910114ORCID,Kim Yujeong12345ORCID,Yoon Chungwoon6784ORCID,Lee Seung Jae6784ORCID,Kim Sun Hee12345ORCID

Affiliation:

1. Western Seoul Center

2. Korea Basic Science Institute (KBSI)

3. Seoul 03759

4. Rep. of Korea

5. Department of Chemistry and Nano Science

6. Department of Chemistry and Institute of Molecular Biology and Genetics

7. Jeonbuk National University

8. Jeonju 54896

9. Department of Chemistry

10. Sunchon National University

11. Suncheon 57922

Abstract

The electronic structures of two cofactors, the FAD radical and [2Fe–2S]+ of reduced MMOR from Methylosinus sporium strain 5 were investigated by advanced EPR spectroscopy. The findings provide long overdue detailed structural information of MMOR.

Funder

National Research Foundation of Korea

Ministry of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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