Controlling the hydrogenolysis of silica-supported tungsten pentamethyl leads to a class of highly electron deficient partially alkylated metal hydrides-Reference-Cited by-同舟云学术

Controlling the hydrogenolysis of silica-supported tungsten pentamethyl leads to a class of highly electron deficient partially alkylated metal hydrides

Published:2016 Issue:2 Volume:7 Page:1558-1568
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Maity Niladri¹²³⁴,Barman Samir¹²³⁴,Callens Emmanuel¹²³⁴,Samantaray Manoja K.¹²³⁴,Abou-Hamad Edy¹²³⁴,Minenkov Yury¹²³⁴,D'Elia Valerio¹²³⁴⁵,Hoffman Adam S.⁶⁷⁸⁹,Widdifield Cory M.¹⁰¹¹¹²¹³,Cavallo Luigi¹²³⁴,Gates Bruce C.⁶⁷⁸⁹,Basset Jean-Marie¹²³⁴

Affiliation:

1. King Abdullah University of Science & Technology

2. KAUST Catalysis Center (KCC)

3. 23955-6900 Thuwal

4. Saudi Arabia

5. Department of Materials Science and Engineering

6. Department of Chemical Engineering and Materials Science

7. University of California at Davis

8. Davis

9. USA

10. Department of Chemistry

11. Durham University

12. Durham DH1 3LE

13. UK

Abstract

Accessing highly electron deficient partially alkylated tungsten hydrides on silica via controlled hydrogenolysis of surface organometallic complex (Si–O–)W(Me)₅.

Funder

King Abdullah University of Science and Technology

U.S. Department of Energy

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC03490F

Reference56 articles.

1. 795. Biscyclopentadienylrhenium hydride