Stereoselective synthesis of alkyl-, aryl-, vinyl- and alkynyl-substituted Z-enamides and enol ethers
Author:
Affiliation:
1. Laboratory of Catalysis and Organic Synthesis
2. Institut des Sciences et Ingénierie Chimique
3. Ecole Polytechnique Fédérale de Lausanne
4. Lausanne
5. Switzerland
Abstract
Highly stereoselective synthesis of Z-enamides and enol ethers at room temperature via an umpolung/cross coupling strategy applicable to drugs and natural products.
Funder
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
École Polytechnique Fédérale de Lausanne
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC05573D
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4. New cross-aldol reactions. Reactions of silyl enol ethers with carbonyl compounds activated by titanium tetrachloride
5. Use of Nonfunctionalized Enamides and Enecarbamates in Asymmetric Synthesis
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