Catalytic oxidation of alkanes by a (salen)osmium(vi) nitrido complex using H2O2 as the terminal oxidant

Author:

Chen Man12345,Pan Yi5674,Kwong Hoi-Ki5674,Zeng Raymond J.12348,Lau Kai-Chung5674,Lau Tai-Chu12345

Affiliation:

1. Advanced Laboratory for Environmental Research & Technology (ALERT)

2. USTC-CityU

3. Suzhou 215123

4. China

5. Department of Biology and Chemistry and Institute of Molecular Functional Materials

6. City University of Hong Kong

7. Hong Kong SAR

8. Department of Chemistry

Abstract

A (salen)osmium(vi) nitrido complex functions as an efficient catalyst for the oxidation of alkanes under ambient conditions using H2O2 as the oxidant.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference24 articles.

1. A. E. Shilov and G. B.Shul’pin, Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes, Kluwer, Boston, 2000

2. K. I. Goldberg and A. S.Goldman, Activation and Functionalization of C–H Bonds, ACS Symposium Series 885, American Chemical Society, Washington, DC, 2004

3. P. R. Ortiz de Montellano , Cytochrome P450. Structure, Mechanism and Biochemistry, Plenum Press, New York, 2005

4. J. L. McLain , J.Lee and J. T.Groves, in Biomimetic Oxidations Catalyzed by Transition Metal Complexes, ed. B. Meunier, Imperial College Press, London, 2000, pp. 91–170

5. Mechanistic Studies on the Hydroxylation of Methane by Methane Monooxygenase

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