Asymmetric synthesis of heteroaryl atropisomers via a gold-catalyzed cycloisomerization–amination cascade reaction-Reference-Cited by-同舟云学术

Asymmetric synthesis of heteroaryl atropisomers via a gold-catalyzed cycloisomerization–amination cascade reaction

Published:2014 Issue:41 Volume:50 Page:5451-5454
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Guo Rui¹²³,Li Kang-Nan¹²³,Liu Bin¹²³,Zhu Hua-Jie⁴⁵⁶⁷⁸,Fan Yu-Meng¹²³,Gong Liu-Zhu¹²³

Affiliation:

1. Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry

2. University of Science and Technology of China

3. Hefei, China

4. Chinese Centre for Chirality

5. Key Laboratory of Medicinal Chemistry and Molecular Diagnostics of Education Administration of China

6. College of Pharmacy Sciences

7. Hebei University

8. Baoding, China

Abstract

The chiral gold(i) complex enables enantioselective cycloisomerization–amination of 2-(alkynyl)phenyl boronic acids and diazenes in high yields.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC01397B

Reference53 articles.

1. E. L. Eliel , S. H.Wilen and M. P.Doyle , Basic Organic Stereochemistry , Wiley , New York , 2001 , p. 608

2. Axial-to-central chirality transfer in cyclization processes

3. Assessing Atropisomer Axial Chirality in Drug Discovery and Development

4. Scalable Total Synthesis and Biological Evaluation of Haouamine A and Its Atropisomer

5. Atroposelective Synthesis of Axially Chiral Biaryl Compounds

Cited by 65 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Catalytic Asymmetric Aza-Electrophilic Additions of 1,1-Disubstituted Styrenes;Journal of the American Chemical Society;2024-07-26

2. Brønsted Acid-Catalyzed Reaction of N-arylnaphthalen-2-amines with Quinone Esters for the Construction of Carbazole and C–N Axially Chiral Carbazole Derivatives;The Journal of Organic Chemistry;2023-02-22

3. Synthetic Strategies to Control C–N Atropisomerism in Acyclic Amines and Amides;Synthesis;2023-02-21

4. Copper-Catalyzed C(sp)–H Bond Hydrazidation;Organic Letters;2023-01-03

5. Gold-Catalyzed Enantioselective Reactions;Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2023