Supramolecular recognition of benzene homologues in a 2D coordination polymer through variable inter-layer π

Supramolecular recognition of benzene homologues in a 2D coordination polymer through variable inter-layer π–π interaction

Published:2018 Issue:24 Volume:20 Page:3313-3317
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Gu Yun-Feng¹²³⁴,Liu Xiao-Ting⁵⁶⁷⁸⁹,Zhang Ying¹²³⁴,Zhang Shu-Ming¹²³⁴^ORCID,Chang Ze⁵⁶⁷⁸⁹^ORCID,Bu Xian-He⁵⁶⁷⁸⁹^ORCID

Affiliation:

1. School of Chemical Engineering and Technology

2. Hebei University of Technology

3. Tianjin 300130

4. China

5. School of Materials Science and Engineering

6. National Institute for Advanced Materials

7. TKL of Metal and Molecular-Based Materials Chemistry

8. Nankai University

9. Tianjin 300350

Abstract

A 2D network 1 was synthesized. After immersing 1 in benzene homologues, the crystal structures of 2 and 3 were gotten, demonstrating that the introduction of benzene homologues has transformed the π–π packing mode, further altering the host framework and fluorescence performance.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CE/C8CE00505B

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3. Metal–Organic Frameworks for Separations