Cyano-decorated ligands: a powerful alternative to fluorination for tuning the photochemical properties of cyclometalated Ir(iii) complexes-Reference-Cited by-同舟云学术

Cyano-decorated ligands: a powerful alternative to fluorination for tuning the photochemical properties of cyclometalated Ir(iii) complexes

Published:2016 Issue:25 Volume:45 Page:10411-10419
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mills Isaac N.¹²³⁴,Kagalwala Husain N.¹²³⁴,Bernhard Stefan¹²³⁴

Affiliation:

1. Carnegie Mellon University

2. Department of Chemistry

3. Pittsburgh

4. USA

Abstract

Two bis-cyclometalated Ir(iii) photocatalysts were synthesized with nitrile moieties which imparted remarkable photophysical properties over conventional fluorinated ligands.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01516F

Reference48 articles.

1. Half-Sandwich Iridium Complexes for Homogeneous Water-Oxidation Catalysis

2. Me2–NHC based robust Ir catalyst for efficient water oxidation

3. Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation

4. Cyclometalated Iridium(III) Aquo Complexes: Efficient and Tunable Catalysts for the Homogeneous Oxidation of Water

5. Photolytic water oxidation catalyzed by a molecular carbene iridium complex

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