Expanding the horizons of porphyrin metal–organic frameworks via catecholate coordination: exploring structural diversity, material stability and redox properties

Author:

De Siddhartha1,Mouchaham Georges2,Liu Fangbing1,Affram Maame2,Abeykoon Brian1,Guillou Nathalie2,Jeanneau Erwann1,Grenèche Jean-Marc3,Khrouz Lhoussain4,Martineau-Corcos Charlotte2,Boudjema Lotfi5,Salles Fabrice5ORCID,Salcedo-Abraira Pablo6ORCID,Valente Gonçalo7,Souto Manuel7ORCID,Fateeva Alexandra1ORCID,Devic Thomas6ORCID

Affiliation:

1. Laboratoire des Multimatériaux et Interfaces, Université Lyon, Université Claude Bernard Lyon 1, UMR CNRS 5615, F-69622 Villeurbanne, France

2. Institut Lavoisier de Versailles, UMR 8180 CNRS UVSQ, Université Paris-Saclay, 45 Avenue des Etats-Unis, 78035 Versailles, France

3. Institut des Molécules et Matériaux du Mans, IMMM UMR CNRS 6283, Le Mans Université, Le Mans Cedex 9 F-72085, France

4. ENS de Lyon, CNRS, Université Claude Bernard Lyon 1, Laboratoire de Chimie UMR 5182, F-69342 Lyon, France

5. ICGM, Univ. Montpellier, CNRS, ENSCM, Montpellier, France

6. Nantes Université, CNRS, Institut des Matériaux de Nantes Jean Rouxel, IMN, F-44000 Nantes, France

7. Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, Aveiro, 3810-393, Portugal

Abstract

Three novel MOF phases based on catecholate porphyrin and M(iii) cations are isolated. Their properties are elucidated through comprehensive structural and physical analyses, and a high surface area and reversible redox activity are evidenced.

Funder

European Research Council

Agence Nationale de la Recherche

Fundação para a Ciência e a Tecnologia

Centro de Investigação em Materiais Cerâmicos e Compósitos

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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