Iron catalyzed β-C(sp2)–H alkylation of enamides-Reference-Cited by-同舟云学术

Iron catalyzed β-C(sp2)–H alkylation of enamides

Published:2021 Issue:37 Volume:45 Page:17475-17482
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Bertho Sylvain¹,Maazaoui Radhouan¹,Torun Damla¹,Dondasse Ismaël¹,Abderrahim Raoudha²,Nicolas Cyril¹,Gillaizeau Isabelle¹^ORCID

Affiliation:

1. Institut de Chimie Organique et Analytique, UMR 7311 CNRS, rue de Chartes, Université d’Orléans, F-45067 Orléans Cedex 2, France

2. Université de Carthage, Faculté des Sciences de Bizerte, Laboratoire de Synthèse Hétérocyclique, 7021 Jarzouna, Bizerte, Tunisia

Abstract

An attractive and cheap alternative approach was developed for the β-C(sp2)–H (fluoro)alkylation of a range of cyclic and acyclic non-aromatic enamides using either FeCl2 as a catalyst or a stoichiometric amount of nontoxic iron powder.

Funder

Agence Nationale de la Recherche

Labex

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D1NJ03673D

Reference37 articles.

1. Cu-mediated enamide formation in the total synthesis of complex peptide natural products

2. Recent advances in the direct β-C(sp2)–H functionalization of enamides

3. Total Synthesis of Natural Products Containing Enamine or Enol Ether Derivatives

4. Enamides and dienamides in phosphoric acid-catalysed enantioselective cycloadditions for the synthesis of chiral amines

Cited by 14 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. α‐Halocarbonyls as a Valuable Functionalized Tertiary Alkyl Source;ChemistryOpen;2024-07-11

2. Advancement in the C–H bond alkylation of (hetero)arenes catalyzed by the most abundant transition metal–iron;Organic Chemistry Frontiers;2024

3. I₂ or I₂/PIFA one-pot induced system for rapid synthesis of chalcogenated enamides, uracils or 2-pyridones under mild conditions;New Journal of Chemistry;2024

4. Iron-Catalyzed Functionalization of Heterocycles Through C─H Activation;Topics in Heterocyclic Chemistry;2024

5. Regioselective Carbozincation and Further Functionalization of Allenamides Catalyzed by an N‐Heterocyclic Carbene (NHC)‐Copper Complex;Asian Journal of Organic Chemistry;2023-09-22