Trifluoromethylation of α-diazoesters and α-diazoketones with fluoroform-derived CuCF3: synergistic effects of co-solvent and pyridine as a promoter-Reference-Cited by-同舟云学术

Trifluoromethylation of α-diazoesters and α-diazoketones with fluoroform-derived CuCF3: synergistic effects of co-solvent and pyridine as a promoter

Published:2019 Issue:1 Volume:6 Page:27-31
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Ma Qiao¹²³⁴,Tsui Gavin Chit¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. The Chinese University of Hong Kong

3. New Territories

4. Hong Kong SAR

Abstract

Fluoroform-derived CuCF₃ can efficiently trifluoromethylate α-diazoesters and α-diazoketones. The key is the use of co-solvent and pyridine as a promoter.

Funder

Research Grants Council, University Grants Committee

Chinese University of Hong Kong

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C8QO00834E

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