Visible light-mediated cross-coupling of electrophiles: synthesis of α-amino amides from isocyanates and ketimines-Reference-Cited by-同舟云学术

Visible light-mediated cross-coupling of electrophiles: synthesis of α-amino amides from isocyanates and ketimines

Published:2021 Issue:6 Volume:8 Page:1227-1232
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhu Junli¹²³⁴⁵,Dai Cancan¹²³⁴⁵,Ma Mengyue⁶⁷⁸⁹¹⁰,Yue Yanni⁶⁷⁸⁹¹⁰,Fan Xinyuan¹²³⁴⁵^ORCID

Affiliation:

1. Synthetic and Functional Biomolecules Center

2. Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education

3. Beijing National Laboratory for Molecular Sciences

4. College of Chemistry and Molecular Engineering

5. Peking University

6. Institute of Advanced Synthesis

7. School of Chemistry and Molecular Engineering

8. Nanjing Tech University

9. Nanjing 211816

10. P. R. China

Abstract

Cross-couplings between the electrophilic ketimines and isocyanates are achieved via the visible light-mediated reactivity inversion of the ketimines, affording the desired α-amino amides in high yields, with both metal and metal-free systems.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

State Key Laboratory of Drug Research

Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D0QO01620A

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