Solvent strategy for unleashing the Lewis acidity of titanocene dichloride for rapid Mannich reactions-Reference-Cited by-同舟云学术

Solvent strategy for unleashing the Lewis acidity of titanocene dichloride for rapid Mannich reactions

Published:2016 Issue:19 Volume:6 Page:15298-15303
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Wu Ya¹²³⁴⁵,Wang Xiu¹²³⁴⁵,Luo Yanlong¹²³⁴⁵,Wang Jing¹²³⁴⁵,Jian Yajun¹²³⁴⁵,Sun Huaming¹²³⁴⁵,Zhang Guofang¹²³⁴⁵,Zhang Weiqiang¹²³⁴⁵,Gao Ziwei¹²³⁴⁵

Affiliation:

1. Key Laboratory of Applied Surface and Colloid Chemistry

2. MOE

3. School of Chemistry and Chemical Engineering

4. Shaanxi Normal University

5. Xi'an 710062

Abstract

The remarkable activation effect of alcohol solvent on kinetically inert titanocene dichloride was found to promote rapid three-component Mannich reactions.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA27094D

Reference45 articles.

1. Cooperative catalysis by carbenes and Lewis acids in a highly stereoselective route to γ-lactams

2. Development of Novel Lewis Acid Catalysts for Selective Organic Reactions in Aqueous Media

3. Combining transition metal catalysis and organocatalysis – an update

4. Synthesis and structure of air-stable Lewis acidic binuclear complex of zirconocene pentafluorophenylsulfonate and its catalytic application in the allylation of carbonyl compounds with tetraallyltin

5. Effect of Solvent and Ancillary Ligands on the Catalytic H/D Exchange Reactivity of Cp*IrIII(L) Complexes

Cited by 13 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Selective synthesis of benzimidazoles and benzodiazepines catalyzed by Brønsted Acid/ base-cooperative Titanocene dichloride;Molecular Catalysis;2022-05

2. An Efficient Synthesis of Heterogeneous and Hard Bound Ti IV ‐MCM‐41 Catalyzed Mannich Bases and π‐Conjugated Imines;ChemistrySelect;2021-12-23

3. A sustainable water-tolerant catalyst with enhanced Lewis acidity: Dual activation of Cp2TiCl2 via ligand and solvent;Molecular Catalysis;2020-12

4. Sulfanilic acid catalysed one‐pot three‐component Mannich reaction for synthesis of β‐amino ketones;Vietnam Journal of Chemistry;2020-10

5. Nanospheric heterogeneous acid-enabled direct upgrading of biomass feedstocks to novel benzimidazoles with potent antibacterial activities;Industrial Crops and Products;2020-08