Electrocatalytic proton-reduction behaviour of telluride-capped triiron clusters: tuning of overpotentials and stabilization of redox states relative to lighter chalcogenide analogues

Author:

Rahaman Ahibur12345,Lisensky George C.2678ORCID,Browder-Long Jess2678,Hrovat David A.9101182,Richmond Michael G.210118,Nordlander Ebbe12345ORCID,Hogarth Graeme2121314ORCID

Affiliation:

1. Chemical Physics

2. Department of Chemistry

3. Lund University

4. SE-221 00 Lund

5. Sweden

6. Beloit College

7. Beloit

8. USA

9. Center for Advanced Scientific Computing and Modeling

10. University of North Texas

11. Denton

12. King's College London

13. London SE1 1DB

14. UK

Abstract

Electrocatalytic proton reduction catalyzed by [Fe3(CO)93-Te)2], and a number of its phosphine and diphosphine derivatives, has been studied.

Funder

European Commission

Royal Society

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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