Effect of aromatic ring fluorination on CH⋯π interactions: microwave spectrum and structure of the 1,2-difluorobenzene⋯acetylene dimer-Reference-Cited by-同舟云学术

Effect of aromatic ring fluorination on CH⋯π interactions: microwave spectrum and structure of the 1,2-difluorobenzene⋯acetylene dimer

Published:2016 Issue:35 Volume:18 Page:24290-24298
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Akmeemana Anuradha G.¹²³,Kang Justin M.⁴⁵³,Dorris Rachel E.¹²³,Nelson Rebecca D.¹²³,Anderton Ashley M.¹²³,Peebles Rebecca A.¹²³,Peebles Sean A.¹²³,Seifert Nathan A.⁴⁶⁷³,Pate Brooks H.⁴⁶⁷³

Affiliation:

1. Department of Chemistry, Eastern Illinois University

2. Charleston

3. USA

4. Department of Chemistry and Biochemistry

5. Oberlin

6. University of Virginia

7. Charlottesville

Abstract

The H⋯π distance increases ino-C₆H₄F₂⋯HCCH, compared to C₆H₅F⋯HCCH or C₆H₆⋯HCCH, consistent with weaker interactions with increased ring fluorination.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP04737H

Reference49 articles.

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3. Pushing the Limits of a Molecular Mechanics Force Field To Probe Weak CH···π Interactions in Proteins

4. Benzene⋯acetylene: a structural investigation of the prototypical CH⋯π interaction

5. Effect of aromatic ring fluorination on CH⋯π interactions: rotational spectrum and structure of the fluorobenzene⋯acetylene weakly bound dimer

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