Enhancing ionic conductivity and suppressing Li dendrite formation in lithium batteries using a vinylene-linked covalent organic framework solid polymer electrolyte

Author:

Yang Jin1ORCID,Lin Chenxiao23ORCID,Wang Yonglei2ORCID,Xu Yaolin2ORCID,Pham Duong Tung2,Meng Xiangqi2,Tran Khanh Van2ORCID,Cao Sijia24,Kardjilov Nikolay2ORCID,Hilger André2,Epping Jan Dirk1,Manke Ingo2ORCID,Thomas Arne1ORCID,Lu Yan254ORCID

Affiliation:

1. Department of Chemistry/Functional Materials, Technische Universität Berlin, Hardenbergstraße 40, 10623 Berlin, Germany

2. Institute of Electrochemical Energy Storage, Helmholtz-Zentrum Berlin für Materialien und Energie, Hahn-Meitner-Platz 1, 14109 Berlin, Germany

3. College of New Energy, Ningbo University of Technology, 315336 Ningbo, China

4. Helmholtz Institute for Polymers in Energy Applications (HIPOLE), Philosophenweg 7b, 07743 Jena, Germany

5. Institute for Technical and Environmental Chemistry, Friedrich-Schiller-Universität Jena, Philosophenweg 7b, 07743 Jena, Germany

Abstract

A novel solid polymer electrolyte based on chemically stable vinylene-linked covalent organic framework was developed, demonstrating enhanced Li+ conductivity and improved battery performance.

Funder

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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