Facet- and structure-dependent catalytic activity of cuprous oxide/polypyrrole particles towards the efficient reduction of carbon dioxide to methanol

Author:

Periasamy Arun Prakash1234,Ravindranath Rini12345,Senthil Kumar Sakkarapalayam Murugesan6789,Wu Wen-Ping1234,Jian Ting-Rui1234,Chang Huan-Tsung12341ORCID

Affiliation:

1. Department of Chemistry

2. National Taiwan University

3. Taipei 106

4. Taiwan

5. Nanoscience and Technology Program

6. Materials Electrochemistry Division

7. CSIR-Central Electrochemical Research Institute

8. Karaikudi-630 003

9. India

Abstract

Cu2O(OL-MH)/Ppy particles selectively reduce CO2to methanol with a faradaic efficiency of 93 ± 1.2% due to an efficient anion exchange mechanism, dominant low-index (111) facets and high-index (311), (211) facets of Cu2O.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Reference95 articles.

1. Beyond Oil and Gas: The Methanol Economy

2. Recent progress in the electrochemical conversion and utilization of CO2

3. Electrochemical Reduction of Carbon Dioxide on Various Metal Electrodes in Low‐Temperature Aqueous  KHCO 3 Media

4. Y. Hori , in Handbook of Fuel Cells: Fundamentals, Technology and Application , ed. A. L. Wolf Vielstich , A. Lamm and H. A. Gasteiger , Wiley , West Sussex, England , 2003 , vol. 2 , pp. 720–733

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